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Beilstein J. Org. Chem. 2013, 9, 1226–1234, doi:10.3762/bjoc.9.139
Graphical Abstract
Scheme 1: RAFT polymerization and silica-supported RAFT polymerization of vinylbenzyl chloride (VBC).
Figure 1: Evolution of number-average molecular weight (Mn) and Mw/Mn values of the poly(VBC) chains obtained...
Figure 2: Conversion and ln([M]0/[M]) versus time for AIBN-initiated, PABTC-mediated polymerization of VBC at...
Figure 3: AIBN-initiated, PABTC-mediated polymerization of VBC with (triangles, DP 4,400) and without (circle...
Figure 4: Evolution of molecular weights of free and grafted poly(VBC) chains with conversion.
Figure 5: Plot of the average diameter and PDI of particles recovered from silica-supported RAFT polymerizati...
Figure 6: TEM micrographs of particles (A) after 2 hours and (B) after 21 hours of VBC polymerization. Scale ...